The ratio of the isomers is determined by their relative thermodynamic stabilities. It should ... Apparently, the formation of more thermodynamically stable alkenes is the driving force of the isomerisation in both cases. 2. Electrophilic sulfenylation of allenes It is of note that reactions of sulfenyl halides with conjugated and non-conjugated dienes do not usually afford vinyl sulfides; therefore, electrophilic sulfenylation of these unsaturated compounds is not considered in this review. Hereanbsp;...
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